Open AccessA Clear Insight into the Distinguishing CO2 Capture by Two Isostructural DyIII–Carboxylate Coordination Frameworks
Author(s) -
Xi Wang,
Min Chen,
Miao Du
Publication year - 2016
Publication title -
inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 233
eISSN - 1520-510X
pISSN - 0020-1669
DOI - 10.1021/acs.inorgchem.6b00760
Subject(s) - isostructural , chemistry , carboxylate , sorption , selectivity , crystallography , stereochemistry , crystal structure , organic chemistry , catalysis , adsorption
Two isostructural the-type Dy(III) coordination networks were successfully constructed based on a pair of analogous tribenzoate bridging ligands with phenyl and triazinyl central spacers. Notably, the active triazinyl group can obviously enhance the capability and selectivity of CO2 sorption for the porous framework.
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