Homolytic N–H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species | Zendy

Markus G. Scheibel | Zendy; Josh Abbenseth | Zendy; Markus Kinauer | Zendy; Frank W. Heinemann | Zendy; Christian Würtele | Zendy; Bas de Bruin | Zendy; Sven Schneider | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Homolytic N–H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species

Author(s) -

Markus G. Scheibel,

Josh Abbenseth,

Markus Kinauer,

Frank W. Heinemann,

Christian Würtele,

Bas de Bruin,

Sven Schneider

Publication year - 2015

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/acs.inorgchem.5b00829

Subject(s) - chemistry , imide , amide , homolysis , iridium , ammonia , nitride , polymer chemistry , medicinal chemistry , inorganic chemistry , organic chemistry , catalysis , radical , layer (electronics)

The redox series [Ir(n)(NHx)(PNP)] (n = II-IV, x = 3-0; PNP = N(CHCHPtBu2)2) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir(III) imido species [Ir(NH)(PNP)] is not stable but undergoes disproportionation to the respective Ir(II) amido and Ir(IV) nitrido species. N-H bond strengths are estimated upon reaction with hydrogen atom transfer reagents to rationalize this observation and are used to discuss the reactivity of these compounds toward E-H bond activation.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research