English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Analysis of the bonding contributions in molecules [M III Cp*(L)XY] (M = Rh, Ir; Cp* = C 5 Me 5 ; L = CO, CN - , CNR) has uncovered a rich variety of types of interaction that seem to have escaped detection so far, in spite of the continuous popularity of cyclopentadienyl transition-metal complexes since the 1970s. At variance with the M-C≡O bond in square-planar systems, which shows typical metal-to-CO π-back-donation, the nonorthogonal arrangement of the Cp* plane and Rh-C≡O fragment and the pseudooctahedral geometry lead to the observation of many direct lateral donations from other ligands that do not involve the metal orbitals, and we name side donations, for instance, Cp* → π*(CO), Cl → π*(CO), and F → π*(CO). Hybrid donations partially involving the metal, M-C aryl → π*(CO), are also observed. The summation of multiple contributions other than back-donation can easily account for about 20% of the electron donation to the π*(C≡O) orbitals.

inorganic chemistry

Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*M<sup>III</sup>(L)XY] (M = Rh, Ir) Complexes with CO, CN<sup>–</sup>, and CNR Ligands. A Window to Cis Influence

Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN–, and CNR Ligands. A Window to Cis Influence

Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*M^III(L)XY] (M = Rh, Ir) Complexes with CO, CN^–, and CNR Ligands. A Window to Cis Influence