Characterization of and Structural Insight into Struvite-K, MgKPO4·6H2O, an Analogue of Struvite

Struvite-K (MgKPO 4 ·6H 2 O) is a magnesium potassium phosphate mineral with naturally cementitious properties, which is finding increasing usage as an inorganic cement for niche applications including nuclear waste management and rapid road repair. Struvite-K is also of interest in sustainable phosphate recovery from wastewater and, as such, a detailed knowledge of the crystal chemistry and high-temperature behavior is required to support further laboratory investigations and industrial applications. In this study, the local chemical environments of synthetic struvite-K were investigated using high-field solid-state 25 Mg and 39 K MAS NMR techniques, alongside 31 P MAS NMR and thermal analysis. A single resonance was present in each of the 25 Mg and 39 K MAS NMR spectra, reported here for the first time alongside the experimental and calculated isotropic chemical shifts, which were comparable to the available data for isostructural struvite (MgNH 4 PO 4 ·6H 2 O). An in situ high-temperature XRD analysis of struvite-K revealed the presence of a crystalline-amorphous-crystalline transition that occurred between 30 and 350 °C, following the single dehydration step of struvite-K. Between 50 and 300 °C, struvite-K dehydration yielded a transient disordered (amorphous) phase identified here for the first time, denoted δ-MgKPO 4 . At 350 °C, recrystallization was observed, yielding β-MgKPO 4 , commensurate with an endothermic DTA event. A subsequent phase transition to γ-MgKPO 4 was observed on further heating, which reversed on cooling, resulting in the α-MgKPO 4 structure stabilized at room temperature. This behavior was dissimilar from that of struvite exposed to high temperature, where NH 4 liberation occurs at temperatures >50 °C, indicating that struvite-K could potentially withstand high temperatures via a transition to MgKPO 4 .