Ytterbium-Centered Isotopic Enrichment Leading to a Zero-Field Single-Molecule Magnet
Author(s) -
Jessica Flores González,
Haiet Douib,
Boris Le Guennic,
Fabrice Pointillart,
Olivier Cador
Publication year - 2021
Publication title -
inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 233
eISSN - 1520-510X
pISSN - 0020-1669
DOI - 10.1021/acs.inorgchem.0c02652
Subject(s) - ytterbium , chemistry , magnetization , relaxation (psychology) , condensed matter physics , magnet , quantum tunnelling , molecule , spin (aerodynamics) , magnetic field , physics , quantum mechanics , organic chemistry , psychology , social psychology , doping , thermodynamics
An unprecedented combination of isotopic enrichment and magnetic dilution approaches for a prolate ytterbium(III)-based complex was performed. It results in the appearance of the first observations of a nuclear spin effect on both quantum tunneling of magnetization and slow magnetic relaxation for an ytterbium complex under a zero applied field.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom