English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The existence of a novel double-molybdate phase with a palmierite-type structure, Cs 2 Ba(MoO 4 ) 2 , is revealed in this work, and its structural properties at room temperature have been characterized in detail using X-ray and neutron diffraction measurements. In addition, its thermal stability and thermal expansion are investigated in the temperature range 298-673 K using high-temperature X-ray diffraction, leading to the volumetric thermal expansion coefficient α  V  ≈ 43.0 × 10 -6 K -1 . The compound's standard enthalpy of formation at 298.15 K has been obtained using solution calorimetry, which yielded Δ f  H  m °(Cs 2 Ba(MoO 4 ) 2 , cr, 298.15 K) = -3066.6 ± 3.1 kJ· mol -1 , and its standard entropy at 298.15 K has been derived from low-temperature (2.1-294.3 K) thermal-relaxation calorimetry as S  m °(Cs 2 Ba(MoO 4 ) 2 , cr, 298.15 K) = 381.2 ± 11.8 J K -1 mol -1 .

Report of the Double-Molybdate Phase Cs2Ba(MoO4)2 with a Palmierite Structure and Its Thermodynamic Characterization

Report of the Double-Molybdate Phase Cs₂Ba(MoO₄)₂ with a Palmierite Structure and Its Thermodynamic Characterization