Open AccessDesign of a Process for Supercritical Water Desalination with Zero Liquid Discharge
Author(s) -
Samuel O. Odu,
Aloijsius G.J. van der Ham,
S.J. Metz,
Sascha R.A. Kersten
Publication year - 2015
Publication title -
industrial and engineering chemistry research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.878
H-Index - 221
eISSN - 1520-5045
pISSN - 0888-5885
DOI - 10.1021/acs.iecr.5b00826
Subject(s) - desalination , supercritical fluid , process engineering , process (computing) , environmental science , multiple effect distillation , energy consumption , wastewater , waste management , environmental engineering , chemistry , computer science , engineering , organic chemistry , electrical engineering , biochemistry , membrane , operating system
Conventional desalination methods have a major drawback; the production of a liquid waste stream which must be disposed. The treatment of this waste stream has always presented technical, economic, and environmental challenges. The supercritical water desalination (SCWD) process meets these challenges as it allows for the treatment of salt-water streams with zero liquid discharge (ZLD). An experimental apparatus has been designed, built, and operated to show the proof of principle of the SCWD process using NaCl–H2O as a model solution. Next, a SCWD process with a two-stage separation step was designed. Enthalpy calculations for a 3.5 wt % NaCl feed and experimental results show that the SCWD process operated at 460 °C and 300 bar will produce drinking water (750 ppm total dissolved solids) and salt crystals (2–5 μm) with an estimated stand-alone thermal energy consumption of 450 MJth/m3 product water
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