Polyvinylidene Fluoride Micropore Membranes as Solid-Phase Extraction Disk for Preconcentration of Nanoparticulate Silver in Environmental Waters | Zendy

Xiaoxia Zhou | Zendy; Yujian Lai | Zendy; Rui Liu | Zendy; Shasha Li | Zendy; Jingwen Xu | Zendy; Jingfu Liu | Zendy

Open Access

Polyvinylidene Fluoride Micropore Membranes as Solid-Phase Extraction Disk for Preconcentration of Nanoparticulate Silver in Environmental Waters

Author(s) -

Xiaoxia Zhou,

Yujian Lai,

Rui Liu,

Shasha Li,

Jingwen Xu,

Jingfu Liu

Publication year - 2017

Publication title -

environmental science and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.851

H-Index - 397

eISSN - 1520-5851

pISSN - 0013-936X

DOI - 10.1021/acs.est.7b04055

Subject(s) - polyvinylidene fluoride , solid phase extraction , elution , extraction (chemistry) , membrane , chromatography , enrichment factor , detection limit , adsorption , aqueous solution , chemistry , materials science , biochemistry , organic chemistry

Efficient separation and preconcentration of trace nanoparticulate silver (NAg) from large-volume environmental waters is a prerequisite for reliable analysis and therefore understanding the environmental processes of silver nanoparticles (AgNPs). Herein, we report the novel use of polyvinylidene fluoride (PVDF) filter membrane for disk-based solid phase extraction (SPE) of NAg in 1 L of water samples with the disk-based SPE system, which consists of a syringe pump and a syringe filter holder to embed the filter membrane. While the PVDF membrane can selectively adsorb NAg in the presence of Ag + , aqueous solution of 2% (m/v) FL-70 is found to efficiently elute NAg. Analysis of NAg is performed following optimization of filter membrane and elution conditions with an enrichment factor of 1000. Additionally, transmission electron microscopy (TEM), UV-vis spectroscopy, and size-exclusion chromatography coupled with ICP-MS (SEC-ICP-MS) analysis showed that the extraction gives rise to no change in NAg size or shape, making this method attractive for practical applications. Furthermore, feasibility of the protocol is verified by applying it to extract NAg in four real waters with recoveries of 62.2-80.2% at 0.056-0.58 μg/L spiked levels. This work will facilitate robust studies of trace NAg transformation and their hazard assessments in the environment.

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