New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines | Zendy

Aaron Trowbridge | Zendy; Scarlett M. Walton | Zendy; Matthew J. Gaunt | Zendy

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New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

Author(s) -

Aaron Trowbridge,

Scarlett M. Walton,

Matthew J. Gaunt

Publication year - 2020

Publication title -

chemical reviews

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 20.528

H-Index - 700

eISSN - 1520-6890

pISSN - 0009-2665

DOI - 10.1021/acs.chemrev.9b00462

Subject(s) - hydroamination , chemistry , catalysis , transition metal , surface modification , photoredox catalysis , amine gas treating , combinatorial chemistry , organic chemistry , organic synthesis , homogeneous catalysis , photocatalysis

Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from simple, readily available feedstocks have become a cornerstone of modern synthetic organic chemistry. In light of the ever-increasing importance of aliphatic amines across the range of chemical sciences, this review aims to provide a concise overview of modern transition-metal catalyzed approaches to alkylamine synthesis and their functionalization. Selected examples of amine bond forming reactions include: (a) hydroamination and hydroaminoalkylation, (b) transition-metal catalyzed C(sp 3 )-H functionalization, and (c) transition-metal catalyzed visible-light-mediated light photoredox catalysis.

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