The Curious Case of Acetaldehyde Phenylhydrazone: Resolution of a 120 Year Old Puzzle where Forms with Vastly Different Melting Points Have the Same Structure
Author(s) -
Carlos Bernades,
Marina Carravetta,
Simon J. Coles,
Ernst R. H. van Eck,
Hugo Meekes,
Manuel E. Minas da Piedade,
Mateusz B. Pitak,
Mike Podmore,
Tobian A. H. De Ruiter,
Leyla-Cann Söğütoğlu,
René R. E. Steendam,
Terry L. Threlfall
Publication year - 2019
Publication title -
crystal growth and design
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.966
H-Index - 155
eISSN - 1528-7505
pISSN - 1528-7483
DOI - 10.1021/acs.cgd.8b01459
Subject(s) - isomerization , chemistry , differential scanning calorimetry , polymorphism (computer science) , acetaldehyde , melting point , stoichiometry , high resolution , crystallography , solid state , liquid state , melting temperature , nmr spectra database , spectral line , thermodynamics , organic chemistry , materials science , catalysis , biochemistry , physics , remote sensing , astronomy , gene , genotype , ethanol , geology , composite material
The solid forms of acetaldehyde phenylhydrazone were investigated in detail over a century ago, with curious results: it was reported that a low melting form could be transformed into a high meltin...
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