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Highly Selective Detection of Benzene, Toluene, and Xylene Hydrocarbons Using Coassembled Microsheets with Förster Resonance Energy Transfer-Enhanced Photostability
Author(s) -
Xiaoling Liu,
Yanjun Gong,
Wei Xiong,
Linfeng Cui,
Ke Hu,
Yanke Che,
Jincai Zhao
Publication year - 2018
Publication title -
analytical chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.117
H-Index - 332
eISSN - 1520-6882
pISSN - 0003-2700
DOI - 10.1021/acs.analchem.8b04680
Subject(s) - förster resonance energy transfer , chemistry , fluorescence , toluene , photochemistry , benzene , molecule , xylene , organic chemistry , optics , physics
In this work, highly photostable and fluorescent coassembled microsheets were fabricated from molecules 1 and 2 for sensitive and selective detection of BTX. We demonstrate that Förster resonance energy transfer (FRET) from nonphotostable 1 to photostable 2 gives rise to the high photostability of 1-2 coassembled microsheets. Furthermore, the combined properties of 1 and 2 components in coassembled microsheets allow distinct responses to BTX and other VOC vapors and thereby yield highly sensitive and selective detection of BTX hydrocarbons via FRET. These findings provide a new approach for the development of photostable fluorescence sensors for hazardous chemicals.

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