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Silver Ions Detection via Nucleolipids Self-Assembly
Author(s) -
Bruno Aliès,
Mohamed Amine Ouelhazi,
Angéline Noireau,
Karen Gaudin,
Philippe Barthélémy
Publication year - 2018
Publication title -
analytical chemistry
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 2.117
H-Index - 332
eISSN - 1520-6882
pISSN - 0003-2700
DOI - 10.1021/acs.analchem.8b04066
Subject(s) - chemistry , moiety , supramolecular chemistry , amphiphile , ion , thioflavin , fluorescence , aqueous solution , metal ions in aqueous solution , liposome , membrane , self assembly , combinatorial chemistry , stereochemistry , molecule , organic chemistry , copolymer , biochemistry , medicine , physics , disease , pathology , quantum mechanics , alzheimer's disease , polymer
A novel hybrid bioinspired amphiphile featuring a cytosine moiety, which self-assembles into liposomes can be used to detect silver ions in aqueous media. The coordination of Ag + ions by the nucleotide moiety increases membrane rigidity, which enhances the fluorescence of a common reporter, Thioflavin T. Ag + can be sensed even at trace concentrations (3 ppb) with great specificity over other metals ions. These nucleotide based supramolecular structures can be used to detect silver ions in drinking water, demonstrating the robustness of this approach.

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