Photophysics and Electrochemiluminescence of Bright Cyclometalated Ir(III) Complexes in Aqueous Solutions | Zendy

J.M. Fernandez-Hernandez | Zendy; Elena Vittoria Longhi | Zendy; Robert Cysewski | Zendy; Federico Polo | Zendy; HansPeter Josel | Zendy; Luisa De Cola | Zendy

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Photophysics and Electrochemiluminescence of Bright Cyclometalated Ir(III) Complexes in Aqueous Solutions

Author(s) -

J.M. Fernandez-Hernandez,

Elena Vittoria Longhi,

Robert Cysewski,

Federico Polo,

HansPeter Josel,

Luisa De Cola

Publication year - 2016

Publication title -

analytical chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.117

H-Index - 332

eISSN - 1520-6882

pISSN - 0003-2700

DOI - 10.1021/acs.analchem.6b00312

Subject(s) - chemistry , iridium , electrochemiluminescence , aqueous solution , ligand (biochemistry) , photochemistry , immunoassay , combinatorial chemistry , electrode , organic chemistry , receptor , catalysis , biochemistry , antibody , immunology , biology

A family of neutral bis-cyclometalated iridium complexes [Ir(C^N)2(LX)] has been investigated as ECL labels under immunoassay conditions. Among them, the complex based on phenylphenanthridine (pphent) as the C^N ligand, exhibits outstanding performance and it is a candidate to substitute the commercially available Ru-based label in diagnostics.

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