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ConspectusMost chemical processes are triggered by electron or charge transfer phenomena (CT). An important class of processes involving CT are chemi-ionization reactions. Such processes are very common in nature, involving neutral species in ground or excited electronic states with sufficient energy (X*) to yield ionic products, and are considered as the primary initial step in flames. They are characterized by pronounced electronic rearrangements that take place within the collisional complex (X···M)* formed by approaching reagents, as shown by the following scheme, where M is an atomic or molecular target: X* + M → (X···M)* → [(X + ···M) ↔ (X···M + )]  e -    →   via  ⁡   e  -   ⁡  CT    (X···M) + + e - → final ions.Despite their important role in fundamental and applied research, combustion, plasmas, and astrochemistry, a unifying description of these basic processes is still lacking. This Account describes a new general theoretical methodology that demonstrates, for the first time, that chemi-ionization reactions are prototypes of gas phase oxidation processes occurring via two different microscopic mechanisms whose relative importance varies with collision energy, E  c , and separation distance, R . These mechanisms are illustrated for simple collisions involving Ne*( 3 P 2,0 ) and noble gases (Ng). In thermal and hyperthermal collisions probing interactions at intermediate and short R , the transition state [(Ne···Ng) + ]  e - is a molecular species described as a molecular ion core with an orbiting Rydberg electron in which the neon reagent behaves as a halogen atom (i.e., F) with high electron affinity promoting chemical oxidation. Conversely, subthermal collisions favor a different reaction mechanism: Ng chemi-ionization proceeds through another transition state [Ne*Ng], a weakly bound diatomic-lengthened complex where Ne* reagent, behaving as a Na atom, loses its metastability and stimulates an electron ejection from M by a concerted emission-absorption of a "virtual" photon. This is a physical radiative mechanism promoting an effective photoionization. In the thermal regime of E  c , there is a competition between these two mechanisms. The proposed method overcomes previous approaches for the following reasons: (1) it is consistent with all assumptions invoked in previous theoretical descriptions dating back to 1970; (2) it provides a simple and general description able to reproduce the main experimental results from our and other laboratories during last 40 years; (3) it demonstrates that the two "exchange" and "radiative" mechanisms are simultaneously present with relative weights that change with E  c (this viewpoint highlights the fact that the "canonical" chemical oxidation process, dominant at high E  c , changes its nature in the subthermal regime to a direct photoionization process; therefore, it clarifies differences between the cold chemistry of terrestrial and interstellar environments and the energetic one of combustion and flames); (4) the proposed method explicitly accounts for the influence of the degree of valence orbital alignment on the selective role of each reaction channel as a function of E  c and also permits a description of the collision complex, a rotating adduct, in terms of different Hund's cases of angular momentum couplings that are specific for each reaction channel; (5) finally, the method can be extended to reaction mechanisms of redox, acid-base, and other important condensed phase reactions.

Quantum-State Controlled Reaction Channels in Chemi-ionization Processes: Radiative (Optical–Physical) and Exchange (Oxidative–Chemical) Mechanisms