Open AccessSynthesis and crystal structure of 2-{5-[2-(2,6-dichlorophenylamino)benzyl]-4-p-tolyl-4H-1,2,4-triazol-3-ylthio}acetate
Author(s) -
Nikhath Fathima,
Noor Shahina Begum,
Gurubasavaraj V. Pujar
Publication year - 2011
Publication title -
journal of saudi chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.67
H-Index - 47
eISSN - 2212-4640
pISSN - 1319-6103
DOI - 10.1016/j.jscs.2011.09.007
Subject(s) - intramolecular force , hydrogen bond , intermolecular force , crystal structure , molecule , chemistry , crystallography , mass spectrum , ring (chemistry) , crystal (programming language) , proton nmr , stereochemistry , mass spectrometry , organic chemistry , chromatography , computer science , programming language
The compound 2-{5-[2-(2,6-dichlorophenylamino)benzyl]-4-p-tolyl-4H-1,2,4-triazol-3-ylthio}acetate has been prepared and characterized by IR, 1H NMR, 13C NMR and mass spectra. The crystal and molecular structure were further confirmed using single crystal X-ray diffraction. The crystal structure has been found to be stabilized by intermolecular C–H···O interaction generating bifurcated hydrogen bonds whereas the C–H···N interactions generate chain of molecules. The intramolecular N–H···N hydrogen bond forms a ring with S(7) graph-set motif
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom