Open AccessIsotope exchange in disulfur monoxide-water charged complexes: A mass spectrometric and computational study
Author(s) -
Giulia de Petris,
Anna Troiani,
Giancarlo Angelini,
Ornella Ursini,
Andreà Bottoni,
Matteo Calvaresi
Publication year - 2007
Publication title -
journal of the american society for mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.961
H-Index - 127
eISSN - 1879-1123
pISSN - 1044-0305
DOI - 10.1016/j.jasms.2007.06.012
Subject(s) - chemistry , mass spectrometry , torr , monoxide , reactivity (psychology) , reaction mechanism , isotope , kinetic isotope effect , ionization , analytical chemistry (journal) , photochemistry , inorganic chemistry , ion , organic chemistry , deuterium , chromatography , catalysis , medicine , physics , alternative medicine , pathology , quantum mechanics , thermodynamics
A hitherto unknown, isotope-exchange reaction is studied in ionized gaseous mixtures containing disulfur monoxide and water. The kinetics, mechanism, and intermediate of the reaction are investigated by experimental and theoretical methods. The reactivity of the S(2)O(*+) cation with water is investigated under a wide range of pressures ranging from 10(-7) to 10(-4) Torr, by FT-ICR, TQ, and high-resolution CAD mass spectrometry. In the high-pressure limit the reaction proves to be a route to strongly bound sulfur-containing species.