Recombination at local aluminum-alloyed silicon solar cell base contacts by dynamic infrared lifetime mapping
Author(s) -
Jens Müller,
Karsten Bothe,
Sebastian Gatz,
Heiko Plagwitz,
Gunnar Schubert,
Rolf Brendel
Publication year - 2011
Publication title -
energy procedia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.474
H-Index - 81
ISSN - 1876-6102
DOI - 10.1016/j.egypro.2011.06.146
Subject(s) - materials science , silicon , saturation current , optoelectronics , dielectric , stack (abstract data type) , aluminium , solar cell , laser , recombination , optics , chemistry , electrical engineering , composite material , voltage , physics , biochemistry , computer science , gene , programming language , engineering
The application of local aluminum (Al)-alloyed contacts to the p-type base of silicon solar cells reduces minority charge carrier recombination due to the formation of a local back surface field (LBSF). We study the recombination properties and formation of base contacts, which are realized by local laser ablation of a dielectric stack (laser contact opening - LCO) and subsequent full area screen printing of Al paste. Based on charge carrier lifetime measurements using the camera-based and calibration-free dynamic infrared lifetime mapping (ILM) technique, we determine contact recombination velocities at the contacts as low as Scont=65cm/s on 200Ωcm float-zone silicon (FZ-Si) and corresponding reverse saturation current densities of J0,cont=900 fA/cm2 on 1.5Ωcm FZ-Si. As a result we show that local contact geometries with point contact radii r>100μm and line contact widths a>80μm are appropriate for lowest contact recombination employing local Al alloyed contacts. Furthermore, complete and high quality laser ablation of the dielectric stack is necessary for the formation of a sufficiently thick LBSF
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