Metal-Catecholate Frameworks as Solid Basic Catalysts | Zendy

Pieterjan Valvekens | Zendy; Maxime Stalpaert | Zendy; Giel De Winter | Zendy; Dirk De Vos | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Metal-Catecholate Frameworks as Solid Basic Catalysts

Author(s) -

Pieterjan Valvekens,

Maxime Stalpaert,

Giel De Winter,

Dirk De Vos

Publication year - 2016

Publication title -

topics in catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.732

H-Index - 111

eISSN - 1572-9028

pISSN - 1022-5528

DOI - 10.1007/s11244-016-0697-5

Subject(s) - physisorption , catalysis , knoevenagel condensation , electronegativity , metal , metal ions in aqueous solution , inorganic chemistry , chemistry , materials science , organic chemistry

Metal catecholate frameworks, based on 2,3,6,7,10,11-hexahydroxytriphenylene and bivalent metal ions (Ni2+, Cu2+, Zn2+, Mg2+, Ca2+, Sr2+ and Ba2+) were synthesized, characterized with powder X-ray diffraction and N2 physisorption, and evaluated as catalysts in Knoevenagel condensation and Michael addition reactions. The large number of catecholate oxygen atoms in these materials resulted in a high catalytic activity which was shown to be a function of both the porosity of the material and the electronegativity of the metal ion.status: publishe

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research