An In-defect complex as a possible explanation for high luminous efficacy of InGaN and AlInN based devices
Author(s) -
P. Keßler,
K. Lorenz,
S. M. C. Miranda,
J. G. Correia,
K. Johnston,
R. Vianden
Publication year - 2010
Publication title -
hyperfine interactions
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.359
H-Index - 48
eISSN - 1572-9540
pISSN - 0304-3843
DOI - 10.1007/s10751-010-0200-9
Subject(s) - indium , materials science , impurity , vacancy defect , dopant , electric field , optoelectronics , crystallography , chemistry , doping , physics , organic chemistry , quantum mechanics
The role of indium in GaN and AlN films is investigated with the method of the perturbed angular correlation (PAC). Using the PAC probe $^{111}$In in addition to indium on substitutional cation sites a large fraction of probes is found in a distinctly different microscopic environment which was attributed to the formation of an indium nitrogen-vacancy (VN) complex. The influence of an electron capture induced after ef fect is ruled out by additional measurements with the PAC probes $^{111m}$Cd and $^{117}$Cd and using GaN with different dopants. It is shown that the VN is not bound to substitutional Cd impurities suggesting that the In-VN complex formation is a particularity of In in GaN and AlN. Finally, a preliminary model is presented to explain the temperature behavior of the electric field gradient, observed in the In-VN complex measured with $^{111}$In
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