Stereoselective Palladium(II)Catalyzed Oxycarbonylation of Unsaturated Polyols | Zendy

Tibor Gracza | Zendy; L’uboš Remeň | Zendy; Peter Szolcsányi | Zendy; Volker Jäger | Zendy; Thomas Hasenöhrl | Zendy

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Stereoselective Palladium(II)Catalyzed Oxycarbonylation of Unsaturated Polyols

Author(s) -

Tibor Gracza,

L’uboš Remeň,

Peter Szolcsányi,

Volker Jäger,

Thomas Hasenöhrl

Publication year - 1997

Publication title -

molecules

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.782

H-Index - 149

eISSN - 1433-1373

pISSN - 1420-3049

DOI - 10.1007/s007830050023

Subject(s) - palladium , stereoselectivity , catalysis , chemistry , combinatorial chemistry , glycoside , organic chemistry

The general approach to optically active anhydroalditols, a class of compounds that have proven most versatile intermediates for C-nucleosides / C-glycosides syntheses is presented. Our entry into this field features the palladium(II)-catalyzed oxycarbonylation of unprotected enitols as key step. The total syntheses of some natural styryl-lactones [(+)-goniofufurone, (+)-7-epi-goniofufurone and (+)-goniopypyrone] have been developed, using oxycarbonylation as key step.

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