Spectral Analysis for Systems of Atoms and Molecules Coupled to the Quantized Radiation Field
Author(s) -
Volker Bach,
Jürg Fröhlich,
Israel Michael Sigal
Publication year - 1999
Publication title -
communications in mathematical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.662
H-Index - 152
eISSN - 1432-0916
pISSN - 0010-3616
DOI - 10.1007/s002200050726
Subject(s) - physics , ground state , excited state , atomic physics , electron , atom (system on chip) , metastability , electromagnetic field , field (mathematics) , bound state , quantum mechanics , mathematics , computer science , pure mathematics , embedded system
: We consider systems of static nuclei and electrons – atoms and molecules – coupled to the quantized radiation field. The interactions between electrons and the soft modes of the quantized electromagnetic field are described by minimal coupling, p→p−e A (x), where A(x) is the electromagnetic vector potential with an ultraviolet cutoff. If the interactions between the electrons and the quantized radiation field are turned off, the atom or molecule is assumed to have at least one bound state. We prove that, for sufficiently small values of the fine structure constant α, the interacting system has a ground state corresponding to the bottom of its energy spectrum. For an atom, we prove that its excited states above the ground state turn into metastable states whose life-times we estimate. Furthermore the energy spectrum is absolutely continuous, except, perhaps, in a small interval above the ground state energy and around the threshold energies of the atom or molecule.
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