Preparation and characterisation of γ-Fe2O3 as tape recording material
Author(s) -
K. Seshan,
M. R. Anantharaman,
V. Shankar Rao,
A. L. Shashimohan,
H. V. Keer,
D. K. Chakrabarty
Publication year - 1981
Publication title -
bulletin of materials science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.35
H-Index - 72
eISSN - 0973-7669
pISSN - 0250-4707
DOI - 10.1007/bf02908495
Subject(s) - acicular , materials science , thermal decomposition , decomposition , ferrous , oxalate , diffraction , composite material , metallurgy , inorganic chemistry , optics , microstructure , organic chemistry , chemistry , physics
Optimum conditions for the preparation of tape recording quality γ-Fe2O3 by the thermal decomposition of ferrous oxalate dihydrate have been established. Formation of the intermediate Fe3O4 which is most important in forming γ-Fe2O3 takes place only in the presence of water vapour. Various stages of decomposition have been characterised by DTA, TG, DTG, and x-ray powder diffraction. The method for the preparation of acicular γ-Fe2O3 that matches very well with the commercial tape recording material has been developed.
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