CH local mode overtone excitations in benzyl chloride—A conformational study | Zendy

Tabish Rasheed | Zendy; V. P. N. Nampoori | Zendy

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CH local mode overtone excitations in benzyl chloride—A conformational study

Author(s) -

Tabish Rasheed,

V. P. N. Nampoori

Publication year - 1994

Publication title -

pramana

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.513

H-Index - 52

ISSN - 0304-4289

DOI - 10.1007/bf02847685

Subject(s) - overtone , benzene , materials science , ring (chemistry) , diffraction , chloride , aryl , absorption (acoustics) , molecular physics , photochemistry , crystallography , chemistry , optics , physics , spectral line , organic chemistry , alkyl , astronomy , metallurgy , composite material

The CH local mode overtone spectrum of benzyl chloride in the visible and NIR regions studied by laser induced thermal lens and conventional NIR absorption is presented. The analysis shows that the −CH2Cl group is symmetrically oriented with respect to the benzene ring, thus finalizing one of the two possible conformational models predicted by electron diffraction studies. The aryl CH bonds have a slightly larger force constant than that in benzene.

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