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Influence of inherent strain on the curie temperature of rare earth ion-doped bismuth vanadate
Author(s) -
K. Sooryanarayana,
T.N.G. Row,
R. Somashekar,
K. B. R. Varma
Publication year - 1998
Publication title -
bulletin of materials science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.35
H-Index - 72
eISSN - 0973-7669
pISSN - 0250-4707
DOI - 10.1007/bf02790353
Subject(s) - materials science , curie temperature , bismuth vanadate , bismuth , crystallite , vanadate , strain (injury) , doping , ion , anisotropy , curie , analytical chemistry (journal) , rare earth , condensed matter physics , metallurgy , optics , ferromagnetism , chemistry , medicine , biochemistry , physics , optoelectronics , organic chemistry , chromatography , photocatalysis , catalysis
X-ray line broadening is found to be an effective parameter to estimate the strain associated with rare earth ion (Gd3+)-doped polycrystalline bismuth vanadate(Bi2VO5.5). The strain increases with increasing Gd3+ concentration. It is anisotropic and found to be maximum in (111) plane. The Curie temperature which is known to decrease with increase in the rare earth ion concentration in these compounds is correlated with increase in strain

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