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Selective monoacetylation of diol compounds by Aspergillus niger lipase
Author(s) -
KwoFeng Hsiao,
FangLin Yang,
ShihHsiung Wu,
KungTsung Wang
Publication year - 1996
Publication title -
biotechnology letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.548
H-Index - 107
eISSN - 1573-6776
pISSN - 0141-5492
DOI - 10.1007/bf00129954
Subject(s) - aspergillus niger , lipase , diol , regioselectivity , chemistry , vinyl acetate , thio , alcohol , triacylglycerol lipase , organic chemistry , aspergillus , propanediol , stereochemistry , enzyme , catalysis , biochemistry , biology , microbiology and biotechnology , polymer , copolymer
The primary monoesters of diol compounds were formed exclusively in the reaction with vinyl acetate and Aspergillus niger lipase for 24~72 h. Various diol compounds which included 1,3-butanediol, 1,4-butanediol, 1,5-hexanediol, 1-phenyl-1,2-ethanediol, 1-phenyl-1,3-propanediol, 2, 3, or 4-hydroxybenzyl alcohol, methyl 2, 3-O-acetyl-D-glycopyranosides and phenyl 1-thio-ß-D-xylopyranoside have been examined and showed nearly 100% regioselectivity.

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