Premium
Insertion of Ruthenium into an inorganic, cyclic biradicaloid
Author(s) -
Oswald Jan,
Scharnhölz Moritz T.,
Coburger Peter,
Beer Henrik,
Bresien Jonas,
Schulz Axel,
Grützmacher Hansjörg
Publication year - 2022
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.202200093
Subject(s) - chemistry , halide , ruthenium , reactivity (psychology) , chloride , single crystal , infrared spectroscopy , inorganic chemistry , crystal structure , crystallography , catalysis , organic chemistry , medicine , alternative medicine , pathology
The reaction between [Ru 2 Cl 2 ( μ 2 ‐Cl) 2 (CO) 6 ] and the biradicaloid [P( μ ‐NTer)] 2 proceeds under insertion of a Ru(II)Cl(CO) 2 fragment into one P−N bond and addition of chloride to the adjacent phosphorus center. Thereby an unprecedented inorganic ruthenacycle is obtained that was investigated by single crystal X‐ray analysis, NMR and IR spectroscopy and DFT calculations. The reactivity of the complex in a halide‐pseudo‐halide exchange reaction and a coordination reaction were investigated.