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Application of CD and Eu 3+ Dual Emission MOF Colorimetric Fluorescent Probe Based on Neural Network in Fe 3+ Detection
Author(s) -
Zheng Yuewei,
Wang Xuan,
Guan Zhihao,
Deng Junjie,
Liu Xinghai,
Li Houbin,
Zhao Pingping
Publication year - 2022
Publication title -
particle and particle systems characterization
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.877
H-Index - 56
eISSN - 1521-4117
pISSN - 0934-0866
DOI - 10.1002/ppsc.202200124
Subject(s) - fluorescence , ethylenediamine , citric acid , metal ions in aqueous solution , aqueous solution , metal organic framework , luminescence , chemistry , metal , linear range , materials science , analytical chemistry (journal) , inorganic chemistry , detection limit , optoelectronics , adsorption , organic chemistry , optics , chromatography , physics
A new highly fluorescent hybrid material (CD@Eu‐MOF) is synthesized by encapsulating carbon dots (CD) prepared from citric acid and ethylenediamine on the basis of a metal‐organic framework (MOF) prepared from Eu 3+ and 1,2,4‐benzenetricarboxylic acid. The prepared composite not only maintains the excellent fluorescence properties of CD and Eu 3+ , respectively, but also forms a dual‐emission fluorescence system, and the system has good stability in an aqueous solution. It is further used as a novel fluorescent probe for the detection of Fe 3+ , which can effectively exclude the interference of other metal ions from the detection, and the intensity ratio of I Eu /I CD of CD@Eu‐MOF material has a good linear relationship with Fe 3+ in the range of 1–200 µ m . In this study, computer vision and backpropagation (BP) neural networks are used to train and fit the sample data, and it is verified that the actual fluorescence color of CD has a good linear relationship with Fe 3+ concentration. In addition, the BP neural network also verifies that the fluorescence spectrum data of CD@Eu‐MOF also have a good linear relationship with Fe 3+ concentration. This study provides a new method for the fabrication of ratio and colorimetric Fe 3+ fluorescence sensors.