Open AccessElectrical conductivity, impedance, and percolation behavior of carbon nanofiber and carbon nanotube containing gellan gum hydrogels
Author(s) -
Warren Holly,
Gately Reece D.,
O'Brien Patrick,
Gorkin Robert,
in het Panhuis Marc
Publication year - 2014
Publication title -
journal of polymer science part b: polymer physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.65
H-Index - 145
eISSN - 1099-0488
pISSN - 0887-6266
DOI - 10.1002/polb.23497
Subject(s) - materials science , carbon nanotube , gellan gum , composite material , electrical resistivity and conductivity , self healing hydrogels , percolation (cognitive psychology) , conductivity , percolation threshold , nanotube , nanofiber , carbon nanofiber , chemical engineering , polymer chemistry , chemistry , food science , neuroscience , electrical engineering , biology , engineering
The electrical impedance behavior of gellan gum (GG), GG–carbon nanotube, and GG–carbon nanofiber hydrogel composites is reported. It is demonstrated that the impedance behavior of these gels can be modeled using a Warburg element in series with a resistor. Sonolysis (required to disperse the carbon fillers) does not affect GG hydrogel electrical conductivity (1.2 ± 0.1 mS/cm), but has a detrimental effect on the gel's mechanical characteristics. It was found that the electrical conductivity (evaluated using impedance analysis) increases with increasing volume fraction of the carbon fillers and decreasing water content. For example, carbon nanotube containing hydrogels exhibited a six‐ to sevenfold increase in electrical conductivity (to 7 ± 2 mS/cm) at water content of 82%. It is demonstrated that at water content of 95 ± 2% the electrical behavior of multiwalled nanotube containing hydrogels transitions (percolates) from transport dominated by ions (owing to GG) to transport dominated by electrons (owing to the carbon nanotube network). © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52 , 864–871