Facile synthesis of fluorene‐based π‐conjugated polymers via sequential bromination/direct arylation polycondensation | Zendy

Saito Hitoshi | Zendy; Kuwabara Junpei | Zendy; Kanbara Takaki | Zendy

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Facile synthesis of fluorene‐based π‐conjugated polymers via sequential bromination/direct arylation polycondensation

Author(s) -

Saito Hitoshi,

Kuwabara Junpei,

Kanbara Takaki

Publication year - 2015

Publication title -

journal of polymer science part a: polymer chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.768

H-Index - 152

eISSN - 1099-0518

pISSN - 0887-624X

DOI - 10.1002/pola.27689

Subject(s) - condensation polymer , fluorene , conjugated system , halogenation , monomer , polymer , yield (engineering) , polymer chemistry , chemistry , surface modification , organic chemistry , one pot synthesis , combinatorial chemistry , materials science , catalysis , metallurgy

The synthesis of fluorene‐based π‐conjugated polymers via sequential bromination and Pd‐catalyzed direct arylation polycondensation was demonstrated; the protocol allows dual functionalization of each aromatic monomer in one‐pot fashion. This synthetic protocol afforded the corresponding polymers with high molecular weights in good yields (up to yield 80%, M n 34,500).

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