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Micron‐sized polystyrene particles by surfactant‐free emulsion polymerization in air: Synthesis and mechanism
Author(s) -
Telford Andrew M.,
Pham Binh T. T.,
Neto Chiara,
Hawkett Brian S.
Publication year - 2013
Publication title -
journal of polymer science part a: polymer chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.768
H-Index - 152
eISSN - 1099-0518
pISSN - 0887-624X
DOI - 10.1002/pola.26841
Subject(s) - emulsion polymerization , polystyrene , emulsion , pulmonary surfactant , chemical engineering , polymer , polymerization , materials science , particle (ecology) , polymer chemistry , particle size , chemistry , composite material , engineering , oceanography , geology
In this study, a novel, robust approach is presented to produce micrometer‐scale‐sized polystyrene particles with narrow size distribution in highly concentrated latexes. The approach could be easily employed by those not skilled in the art to produce large quantities of polymer particles for research applications. A recent hypothesis is corroborated for the mechanism of particle growth in surfactant‐free emulsion polymerization, based on heterocoagulation of precursor particles onto mature ones.

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