High mechanophore content polyester‐acrylate ABA block copolymers: Synthesis and sonochemical activation | Zendy

Kean Zachary S. | Zendy; Ramirez Ashley L. Black | Zendy; Craig Stephen L. | Zendy

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High mechanophore content polyester‐acrylate ABA block copolymers: Synthesis and sonochemical activation

Author(s) -

Kean Zachary S.,

Ramirez Ashley L. Black,

Craig Stephen L.

Publication year - 2012

Publication title -

journal of polymer science part a: polymer chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.65

H-Index - 145

eISSN - 1099-0518

pISSN - 0887-624X

DOI - 10.1002/pola.26148

Subject(s) - copolymer , polyester , acrylate , polymer chemistry , polymer , materials science , block (permutation group theory) , methyl acrylate , chemical engineering , chemistry , polymer science , composite material , geometry , mathematics , engineering

An ABA triblock copolymer with a mechanochemically active gem ‐dichlorocyclopropane rich polyester block is synthesized via chain extension with polymethylacrylate under SET‐LRP conditions. The platform allows for the efficient mechanochemical ring opening of the g DCC groups to 2,3‐dichloroalkenes, a promising approach to the synthesis of high mechanophore content polymers with enhanced stability.

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