New polyimides incorporated with diphenylpyrenylamine unit as fluorophore and redox‐chromophore | Zendy

Kung YiChun | Zendy; Lee WenFu | Zendy; Hsiao ShengHuei | Zendy; Liou GueySheng | Zendy

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New polyimides incorporated with diphenylpyrenylamine unit as fluorophore and redox‐chromophore

Author(s) -

Kung YiChun,

Lee WenFu,

Hsiao ShengHuei,

Liou GueySheng

Publication year - 2011

Publication title -

journal of polymer science part a: polymer chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.768

H-Index - 152

eISSN - 1099-0518

pISSN - 0887-624X

DOI - 10.1002/pola.24652

Subject(s) - alicyclic compound , thermal stability , solvatochromism , glass transition , polymer chemistry , electrochromism , materials science , polymer , chromophore , solubility , arylene , photochemistry , chemistry , organic chemistry , electrode , alkyl , molecule , aryl , composite material

A series of novel polyimides based on N,N ‐di(4‐aminophenyl)‐1‐aminopyrene and aromatic or alicyclic tetracarboxylic dianhydrides were synthesized. The polymers exhibited good solubility in many polar organic solvents and could afford robust films via solution casting. The polyimides derived from aromatic dianhydrides exhibited high thermal stability and high glass‐transition temperatures (333–364 °C). Cyclic voltammetry studies of the polymer films showed that these polyimides are both p and n dopable and have multicolored electrochromic states. For the polyimides derived from alicyclic dianhydrides, they revealed a strong blue‐light emission with high fluorescence quantum yields (ϕ PL > 45%) and a marked solvatochromic behavior. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011

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