Rapid synthesis of block and cyclic copolymers via click chemistry in the presence of copper nanoparticles | Zendy

Pressly Eric D. | Zendy; Amir Roey J. | Zendy; Hawker Craig J. | Zendy

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Rapid synthesis of block and cyclic copolymers via click chemistry in the presence of copper nanoparticles

Author(s) -

Pressly Eric D.,

Amir Roey J.,

Hawker Craig J.

Publication year - 2010

Publication title -

journal of polymer science part a: polymer chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.768

H-Index - 152

eISSN - 1099-0518

pISSN - 0887-624X

DOI - 10.1002/pola.24504

Subject(s) - copolymer , click chemistry , copper , nanoparticle , polymer , yield (engineering) , polymer chemistry , coupling reaction , combinatorial chemistry , chemistry , materials science , nanotechnology , catalysis , organic chemistry , metallurgy

A new method for the rapid and efficient coupling of homopolymers to yield diblock and triblock copolymers as well as cyclic polymers using the 3 + 2 π Huisgen copper catalyzed cycloaddition reaction has been developed. This facile method utilizes commercially available Cu nanoparticles that are tolerant to O 2 , easily removable and recyclable. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011

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