Thiophene–phenylene/naphthalene‐based step‐ladder copolymers | Zendy

Bünnagel Torsten W. | Zendy; Nehls Benjamin S. | Zendy; Galbrecht Frank | Zendy; Schottler Kristina | Zendy; Kudla Christof J. | Zendy; Volk Markus | Zendy; Pina João | Zendy; de Melo João S. Seixas | Zendy; Burrows Hugh D. | Zendy; SCherf Ullrich | Zendy

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Thiophene–phenylene/naphthalene‐based step‐ladder copolymers

Author(s) -

Bünnagel Torsten W.,

Nehls Benjamin S.,

Galbrecht Frank,

Schottler Kristina,

Kudla Christof J.,

Volk Markus,

Pina João,

de Melo João S. Seixas,

Burrows Hugh D.,

SCherf Ullrich

Publication year - 2008

Publication title -

journal of polymer science part a: polymer chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.768

H-Index - 152

eISSN - 1099-0518

pISSN - 0887-624X

DOI - 10.1002/pola.23039

Subject(s) - thiophene , stille reaction , copolymer , phenylene , polymer chemistry , materials science , naphthalene , coupling reaction , polymer , solid state , chemistry , photochemistry , organic chemistry , catalysis , composite material

A series of step‐ladder copolymers based on thiophene–phenylene–thiophene SL1 ‐ SL3 and thiophene–naphthylene–thiophene SL4 repeat units with varying lengths of the oligothiophene segment has been designed and synthesized via a microwave‐assisted Stille‐type cross‐coupling reaction followed by a polymer‐analogous cyclization reaction. The optical properties of the step‐ladder copolymers have been investigated in detail, in particular at low temperature and in the solid‐state. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7342–7353, 2008

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