Synthesis of polybutadiene‐ graft ‐poly(dimethylsiloxane) and polyethylene‐ graft ‐poly(dimethylsiloxane) copolymers with hydrosilylation reactions | Zendy

Ciolino A. E. | Zendy; Pieroni O. I. | Zendy; Vuano B. M. | Zendy; Villar M. A. | Zendy; Vallés E. M. | Zendy

Open Access

Synthesis of polybutadiene‐ graft ‐poly(dimethylsiloxane) and polyethylene‐ graft ‐poly(dimethylsiloxane) copolymers with hydrosilylation reactions

Author(s) -

Ciolino A. E.,

Pieroni O. I.,

Vuano B. M.,

Villar M. A.,

Vallés E. M.

Publication year - 2004

Publication title -

journal of polymer science part a: polymer chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.768

H-Index - 152

eISSN - 1099-0518

pISSN - 0887-624X

DOI - 10.1002/pola.20032

Subject(s) - hydrosilylation , copolymer , polybutadiene , polymer chemistry , macromonomer , silane , materials science , polyethylene , catalysis , chemistry , polymer , organic chemistry , composite material

We report preliminary results for the synthesis of polyethylene‐ graft ‐poly(dimethylsiloxane) copolymers obtained by catalytic hydrogenation of polybutadiene‐ graft ‐poly(dimethylsiloxane) copolymers (PB‐ g ‐PDMS). These last copolymers were synthesized by hydrosilylation reactions between commercial polybutadiene and ω‐silane poly(dimethylsiloxane). The reaction was carried in solution catalyzed by cis ‐dichloro bis(diethylsufide) platinum(II) salt. The PB‐ g ‐PDMS copolymers were analyzed by 1 H and 13 C NMR spectroscopies, and the relative weight percentages of the grafted poly(dimethylsiloxane) macromonomer were determined from the integrated peak areas of the spectra. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2920–2930, 2004

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