Effects of coordinately unsaturated cobalt complexes on radical polymerization of vinyl monomers | Zendy

Bhanu V. A. | Zendy; Kishore K. | Zendy

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Effects of coordinately unsaturated cobalt complexes on radical polymerization of vinyl monomers

Author(s) -

Bhanu V. A.,

Kishore K.

Publication year - 1990

Publication title -

journal of polymer science part a: polymer chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.768

H-Index - 152

eISSN - 1099-0518

pISSN - 0887-624X

DOI - 10.1002/pola.1990.080281308

Subject(s) - cobalt , polymerization , chemistry , acrylamide , monomer , radical , polymer chemistry , radical polymerization , induction period , photochemistry , polymer , organic chemistry , catalysis

The tetrahedral cobalt(II) complexes A‐D are found to possess an unusual coordinately unsaturated nature. These additives significantly inhibit the thermal polymerization of acrylamide and further, they impart significant induction period during AIBN initiated polymerization of MMA and acrylamide. Some evidence has been obtained to show that the additives' effect plausibly results because of the reaction of the coordinately unsaturated cobalt complexes with radicals present in the system.

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