Intrachain chromophore interactions in silanylene‐spaced divinylbenzene copolymers | Zendy

Hwu TsyrYuan | Zendy; Basu Sourav | Zendy; Chen RueyMin | Zendy; Cheng YenJu | Zendy; Hsu JuiHung | Zendy; Fann Wunshain | Zendy; Luh TienYau | Zendy

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Intrachain chromophore interactions in silanylene‐spaced divinylbenzene copolymers

Author(s) -

Hwu TsyrYuan,

Basu Sourav,

Chen RueyMin,

Cheng YenJu,

Hsu JuiHung,

Fann Wunshain,

Luh TienYau

Publication year - 2003

Publication title -

journal of polymer science part a: polymer chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.768

H-Index - 152

eISSN - 1099-0518

pISSN - 0887-624X

DOI - 10.1002/pola.10763

Subject(s) - hydrosilylation , chromophore , copolymer , divinylbenzene , moiety , monomer , polymer chemistry , conjugated system , materials science , chemistry , styrene , polymer , photochemistry , catalysis , organic chemistry

A range of silanylene‐spaced divinylbenzene copolymers ( 1 ) and the corresponding monomers ( 2 ) have been synthesized by the rhodium‐catalyzed hydrosilylation of the corresponding bisalkynes with bissilyl hydrides, and the photophysical properties of 1 and 2 have been investigated. The silicon moiety in 1 serves as an insulating tetrahedral spacer that makes 1 highly folded. The two chromophores may be in close proximity such that a ground‐state intrachain interaction between two conjugated moieties through space might occur. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2218–2231, 2003

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