The manganese complex of 2,3,7,8,12,13,17,18‐octaphenylporphyrin as epoxidation catalyst | Zendy

Sobral Abílio J. F. N. | Zendy; Rocha Gonsalves António M. d'A. | Zendy

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The manganese complex of 2,3,7,8,12,13,17,18‐octaphenylporphyrin as epoxidation catalyst

Author(s) -

Sobral Abílio J. F. N.,

Rocha Gonsalves António M. d'A.

Publication year - 2001

Publication title -

journal of porphyrins and phthalocyanines

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.322

H-Index - 64

eISSN - 1099-1409

pISSN - 1088-4246

DOI - 10.1002/jpp.332

Subject(s) - chemistry , catalysis , manganese , selectivity , chloride , iron(iii) chloride , inorganic chemistry , organic chemistry , medicinal chemistry

The 2,3,7,8,12,13,17,18‐octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß‐pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd.

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