Thrombogenesis: An epitaxial phenomena. I | Zendy

Barenberg S. A. | Zendy; Anderson J. M. | Zendy; Mauritz K. A. | Zendy

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Thrombogenesis: An epitaxial phenomena. I

Author(s) -

Barenberg S. A.,

Anderson J. M.,

Mauritz K. A.

Publication year - 1981

Publication title -

journal of biomedical materials research

Language(s) - English

Resource type - Journals

eISSN - 1097-4636

pISSN - 0021-9304

DOI - 10.1002/jbm.820150210

Subject(s) - crystallinity , copolymer , materials science , epitaxy , surface (topology) , ultrastructure , polymer chemistry , molecular dynamics , morphology (biology) , surface energy , chemical physics , chemical engineering , polymer , polymer science , composite material , chemistry , computational chemistry , geometry , medicine , mathematics , layer (electronics) , pathology , biology , engineering , genetics

A semiempirical epitaxial model has been derived which correlates and interrelates the surface free energy, ultrastructural morphology, surface charge, surface chemistry, and surface molecular motions of a model triblock copolymer to thrombogenesis. This paper addresses the aspect of: (1) ultrastructure order versus disorder, (2) primary and secondary molecular motions, (3) surface and side chain chemistry, (4) thrombogenesis, and (5) the derived epitaxial model based on the above observations. This model can be extrapolated to include and predict the relative thrombogenic responses of various crystalline and semicrystalline polymeric substrates, i.e., aliphatic polyolefins, polyurethanes, and polypeptides.

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