1‐Phosphinodiazaphosphene: Synthesis, crystal structure, and bonding properties | Zendy

Altmeyer Oliver | Zendy; Niecke Edgar | Zendy; Nieger Martin | Zendy; Busch Thilo | Zendy; Schoeller Wolfgang W. | Zendy; Stalke Dietmar | Zendy

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1‐Phosphinodiazaphosphene: Synthesis, crystal structure, and bonding properties

Author(s) -

Altmeyer Oliver,

Niecke Edgar,

Nieger Martin,

Busch Thilo,

Schoeller Wolfgang W.,

Stalke Dietmar

Publication year - 1990

Publication title -

heteroatom chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.283

H-Index - 42

eISSN - 1098-1071

pISSN - 1042-7163

DOI - 10.1002/hc.520010212

Subject(s) - chemistry , quantum chemical , crystal structure , base (topology) , crystal (programming language) , crystallography , catalysis , stereochemistry , computational chemistry , molecule , organic chemistry , mathematical analysis , mathematics , computer science , programming language

The iminophosphane, tBu 2 PPNNR 2 (RSiMe 3 ), produced by base‐catalyzed elimination of ClSiMe 3 from the corresponding phosphane, possesses an unusually long PN bond (162 pm), which is in accord with quantum chemical calculations.

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