Open AccessDehydrogenative Sn–E (E = S, Se) bond formation catalyzed by an iron complex
Author(s) -
Itazaki Masumi,
Ogawa Yudai,
Nakamura Wataru,
Nakazawa Hiroshi
Publication year - 2018
Publication title -
heteroatom chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.283
H-Index - 42
eISSN - 1098-1071
pISSN - 1042-7163
DOI - 10.1002/hc.21461
Subject(s) - chemistry , catalysis , crystallography , single crystal , elemental analysis , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry
Iron complex‐catalyzed dehydrogenative Sn–E (E = S, Se) bond formation of hydrostannane with thiol and selenol was achieved. All new compounds were fully characterized using 1 H, 13 C{ 1 H}, 77 Se{ 1 H}, and 119 Sn{ 1 H} NMR measurements and elemental analyses. The structure of 1,1′‐(1,3‐dithia‐2,2‐dibutylstanyl)‐[3]ferrocenophane was confirmed by single‐crystal X‐ray diffraction.