An iterative strategy for the synthesis of oligothiophenes by catalytic cross‐coupling reactions | Zendy

Pinault Thomas | Zendy; Chérioux Frédéric | Zendy; Therrien Bruno | Zendy; SüssFink Georg | Zendy

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An iterative strategy for the synthesis of oligothiophenes by catalytic cross‐coupling reactions

Author(s) -

Pinault Thomas,

Chérioux Frédéric,

Therrien Bruno,

SüssFink Georg

Publication year - 2004

Publication title -

heteroatom chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.283

H-Index - 42

eISSN - 1098-1071

pISSN - 1042-7163

DOI - 10.1002/hc.10224

Subject(s) - heteroatom , chemistry , stille reaction , thiophene , planarity testing , catalysis , sulfur , coupling reaction , combinatorial chemistry , computational chemistry , organic chemistry , crystallography , ring (chemistry)

An iterative strategy for the synthesis of new sulfur‐functionalized oligothiophenes by Suzuki or Stille cross‐coupling reactions was applied to the reaction of 4‐bromo‐tert‐butylphenylthioether with thiophene derivatives. The planarity of the oligothiophenes obtained was confirmed by the single‐crystal X‐ray structure analysis of 2‐(4′‐tert‐butylthiophenyl)thiophene, which shows a potentially large electronic conjugation length. © 2004 Wiley Periodicals, Inc. Heteroatom Chem 15:121–126, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10224

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