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Hollow Carbon Sphere‐Modified Graphitic Carbon Nitride for Efficient Photocatalytic H 2 Production
Author(s) -
Li Jinghua,
Xiong Lunqiao,
Luo Bing,
Jing Dengwei,
Cao Jiamei,
Tang Junwang
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202102330
Subject(s) - photocatalysis , graphitic carbon nitride , calcination , materials science , carbon nitride , quantum yield , carbon fibers , chemical engineering , photochemistry , nanotechnology , catalysis , composite number , chemistry , organic chemistry , composite material , optics , physics , fluorescence , engineering
A novel hybrid photocatalyst composed of hollow carbon nanospheres (NCS) and graphitic carbon nitride (CN) curly nanosheets has been prepared by the calcination of a NCS precursor and freeze‐dried urea. The optimized photocatalyst exhibits an efficient photocatalytic performance under visible light irradiation with a highest H 2 generation rate of 3612.3 μmol g −1 h −1 , leading to an apparent quantum yield of 10.04 % at 420 nm, five times higher than the widely reported benchmark photocatalyst CN (2.01 % AQY). The materials characterization shows that NCS‐modified CN curly nanosheets can promote photoelectron transfer and suppress charge recombination through their special coupling interface and NCS as an electron acceptor, which significantly improves the photocatalytic efficiency. Thus, this study provides an efficient strategy for the design of highly efficient photocatalyst, particularly suitable for a totally metal‐free photocatalytic system.