Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds | Zendy

Demonceau A. | Zendy; Noels A. F. | Zendy; Hubert A. J. | Zendy; Teyssié P. | Zendy

Open Access

Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Author(s) -

Demonceau A.,

Noels A. F.,

Hubert A. J.,

Teyssié P.

Publication year - 1984

Publication title -

bulletin des sociétés chimiques belges

Language(s) - English

Resource type - Journals

ISSN - 0037-9646

DOI - 10.1002/bscb.19840931103

Subject(s) - rhodium , chemistry , insertion reaction , migratory insertion , transition metal , primary (astronomy) , catalysis , medicinal chemistry , stereochemistry , polymer chemistry , organic chemistry , physics , astronomy

Rhodium(II) carboxylates associated with bulky ligands catalyse the insertion of carbalkoxycarbenes (generated from diszoesters) into C‐H bonds of normal and branched alkanes with selectivities differing substantially from those associated with non‐bulky carboxylates.

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