Multi‐Nuclear Relaxation Time Studies in Undercooled Aqueous Electrolytes
Author(s) -
Lang E. W.,
Fink W.,
Radkowitsch H.,
Girlich D.
Publication year - 1990
Publication title -
berichte der bunsengesellschaft für physikalische chemie
Language(s) - English
Resource type - Journals
ISSN - 0005-9021
DOI - 10.1002/bbpc.19900940328
Subject(s) - alkali metal , halide , relaxation (psychology) , aqueous solution , ion , electrolyte , chemical physics , molecular dynamics , materials science , molecule , coordination sphere , inorganic chemistry , chemistry , computational chemistry , organic chemistry , social psychology , electrode , psychology
The dynamic properties of water molecules coordinated to simple ions (alkali‐, alkali earth halides) in undercooled solutions have been investigated with NMR. Relaxation time studies at low temperatures provide details of molecular motions as well as certain features of the local arrangement in the coordination sphere of these ions.
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