Millimeter Wave Spectrum and Structure of Isoselenocyanic Acid, HNCSe | Zendy

Vogt Jürgen | Zendy; Winnewisser Manfred | Zendy

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Millimeter Wave Spectrum and Structure of Isoselenocyanic Acid, HNCSe

Author(s) -

Vogt Jürgen,

Winnewisser Manfred

Publication year - 1984

Publication title -

berichte der bunsengesellschaft für physikalische chemie

Language(s) - English

Resource type - Journals

ISSN - 0005-9021

DOI - 10.1002/bbpc.19840880504

Subject(s) - isotopomers , rotational spectrum , hamiltonian (control theory) , ground state , extremely high frequency , spectral line , distortion (music) , molecule , atomic physics , chemistry , physics , nuclear magnetic resonance , computational chemistry , rotational spectroscopy , quantum mechanics , mathematics , optics , mathematical optimization , amplifier , optoelectronics , cmos

The rotational a‐type spectra of the five most abundant isotopomers of HNCSe were recorded in natural abundance. Using Watson's S‐reduced Hamiltonian the rotational and some centrifugal distortion constants could be determined for the ground vibrational state of the various isotopic species. With the aid of these constants the restructure of HNCSe could be refined and the parameter specifying the quasilinearity of the molecule could be estimated.

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