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Atomic‐Scale Design of Anode Materials for Alkali Metal (Li/Na/K)‐Ion Batteries: Progress and Perspectives
Author(s) -
Olsson Emilia,
Yu Jiale,
Zhang Haiyan,
Cheng HuiMing,
Cai Qiong
Publication year - 2022
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202200662
Subject(s) - anode , materials science , nanotechnology , lithium (medication) , atomic units , alkali metal , density functional theory , battery (electricity) , multiscale modeling , scale (ratio) , ion , potassium ion battery , engineering physics , computational chemistry , thermodynamics , physics , chemistry , electrode , lithium vanadium phosphate battery , medicine , power (physics) , quantum mechanics , endocrinology
The development and optimization of high‐performance anode materials for alkali metal ion batteries is crucial for the green energy evolution. Atomic scale computational modeling such as density functional theory and molecular dynamics allows for efficient and adventurous materials design from the nanoscale, and have emerged as invaluable tools. Computational modeling cannot only provide fundamental insight, but also present input for multiscale models and experimental synthesis, often where quantities cannot readily be obtained by other means. In this review, an overview of three main anode classes; alloying, conversion, and intercalation‐type anodes, is provided and how atomic scale modeling is used to understand and optimize these materials for applications in lithium‐, sodium‐, and potassium‐ion batteries. In the last part of this review, a novel type of anode materials that are largely predicted from density functional theory simulations is presented. These 2D materials are currently in their early stages of development and are only expected to gain in importance in the years to come, both within the battery field and beyond, highlighting the ability of atomic scale materials design.