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Enhancement of Piezoelectricity in Dimensionally Engineered Metal‐Halide Perovskites Induced by Deep Level Defects
Author(s) -
Heo Sung,
Lee Do Yoon,
Lee Dongwook,
Lee Yonghui,
Kim Kihong,
Yun HyunSung,
Paik Min Jae,
Shin Tae Joo,
Oh Hyeon Seung,
Shin Taeho,
Kim Jaekyung,
Kim Seong Heon,
Seok Sang Il,
Nazeeruddin MohammadKhaja
Publication year - 2022
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202200181
Subject(s) - piezoelectricity , materials science , photovoltaics , halide , perovskite (structure) , energy conversion efficiency , optoelectronics , energy transformation , synchrotron , energy harvesting , nanotechnology , photovoltaic system , energy (signal processing) , optics , crystallography , composite material , inorganic chemistry , chemistry , ecology , physics , biology , thermodynamics , statistics , mathematics
Metal halide perovskite solar cells (PSCs) have been considered to be one of the most promising next‐generation energy harvesters over the past decades due to remarkably rapid improvement of power conversion efficiency in photovoltaics. However, energy harvesters based on the solar energy source have an intrinsic environment limitation for indoor applications. A feasible solution to the limitation is to add non‐solar energy harvesting functions to the solar energy harvesters. Here, the piezoelectric properties of two types of metal halide PSCs are investigated, the 3D only and the 3D/2D structure, showing PCEs of 21.3% and 23.2%, respectively. Piezo‐response force microscopy and synchrotron‐based X‐ray diffraction demonstrate that both types of PSC sample have piezoelectricity. Remarkably, the 3D/2D structure has considerably higher piezoelectric amplitude than the 3D‐only. The deep level transient spectroscopy results reveal that the enhancement in the piezoelectricity of the 3D/2D structure originates from Pb Br defects. This study unravels the role of defects in the piezoelectricity of metal halide PSCs and provides a direction to develop the multi‐function energy harvesters based on the PSCs.