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Orders of Recombination in Complete Perovskite Solar Cells – Linking Time‐Resolved and Steady‐State Measurements
Author(s) -
Wolff Christian M.,
Bourelle Sean A.,
Phuong Le Quang,
Kurpiers Jona,
Feldmann Sascha,
Caprioglio Pietro,
Marquez Jose Antonio,
Wolansky Jakob,
Unold Thomas,
Stolterfoht Martin,
Shoaee Safa,
Deschler Felix,
Neher Dieter
Publication year - 2021
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202101823
Subject(s) - charge carrier , perovskite (structure) , recombination , materials science , non radiative recombination , solar cell , carrier lifetime , ultrafast laser spectroscopy , optoelectronics , absorption (acoustics) , superposition principle , perovskite solar cell , spontaneous emission , carrier generation and recombination , chemical physics , atomic physics , spectroscopy , optics , physics , chemistry , silicon , semiconductor , laser , biochemistry , semiconductor materials , quantum mechanics , composite material , gene , crystallography
Ideally, the charge carrier lifetime in a solar cell is limited by the radiative free carrier recombination in the absorber which is a second‐order process. Yet, real‐life cells suffer from severe nonradiative recombination in the bulk of the absorber, at interfaces, or within other functional layers. Here, the dynamics of photogenerated charge carriers are probed directly in pin‐type mixed halide perovskite solar cells with an efficiency >20%, using time‐resolved optical absorption spectroscopy and optoelectronic techniques. The charge carrier dynamics in complete devices is fully consistent with a superposition of first‐, second‐, and third‐order recombination processes, with no admixture of recombination pathways with non‐integer order. Under solar illumination, recombination in the studied solar cells proceeds predominantly through nonradiative first‐order recombination with a lifetime of 250 ns, which competes with second‐order free charge recombination which is mostly if not entirely radiative. Results from the transient experiments are further employed to successfully explain the steady‐state solar cell properties over a wide range of illumination intensities. It is concluded that improving carrier lifetimes to >3 µs will take perovskite devices into the radiative regime, where their performance will benefit from photon‐recycling.