Open AccessFundamental Loading‐Curve Characteristics of the Persistent Phosphor SrAl 2 O 4 :Eu 2+ ,Dy 3+ ,B 3+ : The Effect of Temperature and Excitation Density
Author(s) -
Delgado Teresa,
Gartmann Nando,
Walfort Bernhard,
LaMattina Fabio,
Pollnau Markus,
Rosspeintner Arnulf,
Afshani Jafar,
Olchowka Jacob,
Hagemann Hans
Publication year - 2022
Publication title -
advanced photonics research
Language(s) - English
Resource type - Journals
ISSN - 2699-9293
DOI - 10.1002/adpr.202100179
Subject(s) - phosphor , afterglow , analytical chemistry (journal) , photoluminescence , dopant , trapping , energy transfer , materials science , chemistry , mineralogy , atomic physics , physics , doping , optoelectronics , ecology , gamma ray burst , chromatography , biology , astronomy
The compound SrAl 2 O 4 :Eu 2+ ,Dy 3+ is currently one of the best‐performing persistent phosphors and numerous studies have been performed to understand the mechanisms involved in its afterglow process. One aspect which so far has received only limited attention is the dependence of loading curve characteristics on dopant concentrations. Herein, a detailed study of the loading curves of SrAl 2 O 4 :Eu 2+ ,Dy 3+ as a function of composition, sample temperature, and pump intensity is presented, completed by emission decay and quantum yield measurements. The observed emission decays can be described using the Inokuti−Hirayama equation for a Dexter energy transfer (ET) process. As the Dexter ET rate and the electron transfer rate have a similar radial dependence, the Inokuti−Hirayama equation can also describe the electron transfer process involved for the trapping process. These observations indicate that in this persistent phosphor, the trapping process is a local process; however, different types of traps appear to present different “Dexter” critical radii R 0 . This electron transfer is also temperature dependent, which requires further investigations.